SILLS软件在单个萤石流体包裹体LA-ICP-MS微量元素分析数据处理中的应用     

李阳  邹灏  刘行  蒋修未  李蝶 《岩矿测试》2020,39(2):300-310

近年来激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)应用于单个流体包裹体成分定量分析已成为研究流体包裹体的最佳手段之一。该实验过程和数据处理比较复杂,目前国内外采用的数据分析软件为一款基于MATLAB的SILLS软件,该软件主要是对矿物(锆石)、流体包裹体以及熔体包裹体LA-ICP-MS分析结果进行处理。本文以萤石流体包裹体LA-ICP-MS分析为例,阐述了样品制备与流体包裹体的优选方法,对流体包裹体片厚度以及单个流体包裹体的选取要求作了详细描述,对仪器参数设置、内外标样选取和剥蚀方法等进行了说明。基于SILLS软件采用尖峰消除的方法对待处理数据进行校正,对不同种类型的波峰进行峰宽的选取。在元素比值校正和等效盐度计算过程中,由于被测样品是萤石,Ca元素具有较高的背景值,选择以Na作为流体包裹体的内标元素,以Ca作为寄主矿物的内标元素对寄主矿物浓度进行计算,同时提出以电价平衡代替质量平衡进行等效盐度计算。以上方案提高了LA-ICP-MS分析单个萤石流体包裹体的准确性,有助于解释成矿流体来源和矿床成因等问题。  相似文献   

Refined chronostratigraphy of the late Mesozoic terrestrial strata in South China and its tectono-stratigraphic evolution     

《Gondwana Research》2019

The late Mesozoic terrestrial strata in numerous basins in S (South) China provide important sedimentary archives to understand the tectonic evolution of S China and East Asia. However, establishing regional stratigraphic framework within a basin and precisely correlating strata among basins remain challenging due to limited chronological constraints. In this study, we report zircon U-Pb ages of 21 samples and a compilation of 132 reliable age data from 15 type sections of the volcanic-sedimentary basins in S China. The synthesized geochronology allows us to establish a refined chronostratigraphy for the late Mesozoic terrestrial strata. New calibrated results indicate that most of the lithostratigraphic units are diachronic, laterally stacking, and/or interfingering. Six stacking styles are classified for the relationship of lithostratigraphic units. Analysis of the refined chronostratigraphy and the stratal stacking styles, together with lithological composition, reveals three episodes of tectono-stratigraphic evolution. Episode I (~145–125 Ma) is characterized by intense volcanism, as evidenced by widespread occurrence of volcanic strata and (137–120 Ma) A-type granites, and was probably related to the rollback of the subducting Paleo-Pacific plate; The strata deposited during Episode II (~125–100 Ma) are composed of variegated sediments associated with/without volcanic intercalations in sedimentary faulted-depression basins, indicating the waning of volcanism and tectonism attributed to the ending of the Izanagi/Kula plate subduction; In Episode III (<~100 Ma), red strata occurred along the NE-SW sinistral strike-slip faulting or failed rifting in small basins, which probably resulted from the drastic directional change of the Paleo-Pacific plate subduction from NW to SN.  相似文献   

Nature and Evolution of Pre-Neoproterozoic Continental Crust in South China: A Review and Tectonic Implications     

WANG Kai  DONG Shuwen  YAO Weihu  ZHAO Tianyu 《《地质学报》英文版》2020,94(6):1731-1756

South China as an amalgamation of the Yangtze and Cathaysia blocks is composed of Archean to Mesoproterozoic basement overlain by Neoproterozoic and younger cover. Both the constituent Yangtze and Cathaysia blocks contain well-preserved Neoproterozoic rocks that have been extensively studied in terms of the age and tectonic nature, but less is known about their earlier crustal history due to the incomplete rock record. Recent efforts in investigating the yet survived crustal nature based on isotopic and elemental signatures preserved in igneous and sedimentary rocks have steadily improved our knowledge about the pre-Neoproterozoic continental crustal evolution in South China. In this paper, we summarize the up-to-date pre-Neoproterozoic records, including petrological, geochronological, geochemical and geophysical data, across South China, and discuss its spatiotemporal patterns of the pre-Neoproterozoic crust and the relevant tectonic events. While the xenocrystic/inherited and detrital zircon records suggest widespread Archean (mainly ca. 2.5 Ga) crustal components within both the Yangtze and Cathaysia blocks, exposed Archean rocks are only limited to isolated crustal provinces in the Yangtze Block. These Archean rocks are dominated by TTGs (tonalite-trondhjemite-granodiorite) with varied ages (3.3–2.5 Ga) and zircon Hf isotopes, indicating a compositionally heterogeneous nature of the Archean Yangtze Block and, by inference, the development of multiple ancient terranes. The early Paleoproterozoic (2.4–2.2 Ga) tectonomagmatic events characterize the western Yangtze Block and are supportive of an east-west subdivision of the Yangtze basement, whereas the late Paleoproterozoic (2.1–1.7 Ga) orogeneses may have affected a larger area covering both the western and eastern parts of the Yangtze Block, and also the Cathaysia Block. The eastern Yangtze Block with generally northeastward-younging late Paleoproterozoic magmatism and metamorphism likely experienced a prolonged 2.05–1.75 Ga orogenic process welding the various Archean proto-continents, consistent with the documentation of a buried late Paleoproterozoic orogenic belt imaged by deep seismic profiling from its central part and of a slightly older ophiolitic mélange in the northern part. The Cathaysia Block was probably involved in a short-lived 1.9–1.8 Ga orogenic event. The two orogeneses overlapped in time and may have contributed to the cratonization of a possible unified South China, and are referred to be linked with the assembly of the Nuna Supercontinent. The subsequent late Paleoproterozoic to early Mesoproterozoic rift successions and intrusions (1.7–1.5 Ga) in the southwestern Yangtze Block, and the ca. 1.43 Ga rifting in Hainan Island of the Cathaysia Block could be responses to the Nuna break-up. Late Mesoproterozoic (1.2–1.0 Ga) magmatism of varied age and nature in different localities of the Yangtze Block is reflective of a complex tectonic process in the context of the assembly of the Rodinia Supercontinent. Similar-aged metamorphism (1.3–1.0 Ga) is recorded in Hainan Island, reflecting the Grenvillian continental collision during the Rodinia assembly, but further studies are necessary to better constrain the late Mesoproterozoic tectonic framework of South China.  相似文献   

In situ LA-ICP-MS analyses of mica and wolframite from the Maoping tungsten deposit,southern Jiangxi,China     

Chen  Guanghong  Gao  Jianfeng  Lu  Jianjun  Zhang  Rongqing 《中国地球化学学报》2020,39(6):811-829

Acta Geochimica - The Maoping tungsten deposit is located in the Nanling W–Sn metallogenic belt in South China. Greisen and quartz vein types of mineralization developed in this deposit....  相似文献   

青海共和盆地中三叠世花岗岩组合岩石成因:地球化学、锆石U-Pb年代学及Hf同位素约束   总被引：1，自引：1，他引：0  

陈希节  贠晓瑞  雷敏  蔡志慧  张盛生  刘若涵  李毅兵  何碧竹 《岩石学报》2020,36(10):3152-3170

青海共和盆地位于青藏高原东北缘，以往有关共和盆地及邻区早-中三叠世岩浆岩成因机制的认识分歧较大，且研究主要集中在露头岩石方面。本文以共和盆地干热岩GR1井深部花岗岩岩芯样品作为研究对象，对其进行岩石学、长石电子探针、主微量元素地球化学、锆石U-Pb年代学及Lu-Hf同位素研究。矿物组成及长石电子探针测试结果显示花岗岩主要为奥长花岗岩、英云闪长岩及花岗闪长岩。锆石U-Pb测年结果表明，奥长花岗岩的结晶年龄为236.5±1.7Ma，英云闪长岩的岩浆结晶年龄为241.6±3.0Ma。主、微量元素地球化学显示这些花岗岩主要为准铝质，属于高钾钙碱性系列。全岩Ta-Nb-Hf等不相容元素图解及锆石Hf同位素数据表明共和盆地的236.5~241.6Ma花岗岩显示火山弧及同碰撞花岗岩成分特征，说明中三叠世共和地区发生俯冲-碰撞转换。结合本文数据与区域背景资料，作者认为：共和盆地早-中三叠世花岗岩组合的形成与印支期宗务隆洋的南向俯冲作用密切相关，此时，在宗务隆-青海南山-西秦岭北缘存在统一的大陆边缘弧环境；在236~241Ma时发生俯冲-碰撞转换；晚三叠世时宗务隆-青海南山-西秦岭北缘已处于碰撞期和后碰撞期。  相似文献   

Lithium isotopic evidence for subduction of the Indian lower crust beneath southern Tibet     

《Gondwana Research》2020

Post-collisional K-rich volcanic rocks (KVRs) can provide an opportunity to constrain the architecture of the lithosphere and the mechanisms of plateau uplift. However, their petrogenesis and geodynamic setting remain in dispute. Lithium concentrations and isotopic compositions of 87 potassic, ultrapotassic and Mg-rich potassic volcanic rocks (PVRs, UPVs, and MPRs, respectively) in SW Tibet, along with new Pb–Sr–Nd isotope data and whole-rock analyses, are used to constrain their mantle source and genesis. These rocks are characterized by very similar δ⁷Li values: PVRs vary from −4.9‰ to +3.2‰, UPVs from −3.9‰ to +1.7‰, and MPRs from −1.2‰ to +3.5‰. They can be classified into two groups: Group I (19 out of 87 samples) with heavier δ⁷Li values (+1.0‰ to +3.5‰) similar to those reported for mid-ocean-ridge and ocean-island basalts (MORBs and OIBs, respectively), and Group II (68 out of 87 samples) with lighter values (−4.9‰ to +1.0‰) similar to those of Indian lower crust. These variable isotopic compositions may record the isotopic signature of the early-middle Miocene subcontinental lithospheric mantle (SCLM). This paper demonstrates the existence of isotopically light mantle domains beneath the Lhasa terrane, which were ascribed to the interaction with fluids/melts derived from the subducted Indian lower crust. The modeling curves of Indian lower crust with a metasomatized mantle composition fully account for compositional variations in the PVRs, UPVs, and MPRs. They were generated by the partial melting of SCLM, which was metasomatized by fluids/melts derived from the subducted Indian lower crust (ca. 4–14%, ca. 4–10%, and ca. 6–10% for the PVRs, UPVs, and MPRs, respectively). The Li isotopic data indicate that the Indian lower crust was subducted beneath the central Lhasa subterrane, and this sheds new light on the formation of the Tibet Plateau.  相似文献   

Fingerprinting hydrothermal fluids in porphyry Cu deposits using K and Mg isotopes     

Li  Weiqiang  Zhao  Shugao  Wang  Xiaomin  Li  Shilei  Wang  Guoguang  Yang  Tao  Jin  Zhangdong 《中国科学:地球科学(英文版)》2020,63(1):108-120

In this study, we performed an integrated investigation of K and Mg isotopes in hydrothermally altered rocks from the giant Dexing porphyry Cu deposit in China. Both the altered porphyry intrusion and the surrounding wall rocks exhibit large variations in K and Mg isotope compositions, with δ41K values ranging between-1.02‰ and 0.38‰, and δ26Mg values ranging between-0.49‰ and 0.32‰. The δ41K and δ26Mg values of the majority of altered samples are higher than the isotopic baseline values for upper continental crust. We attribute the general increase in δ41 K and δ26Mg in altered rocks to hydrothermal alteration,which caused preferential incorporation of heavy K and Mg isotopes in alteration products, particularly phyllosilicates. However,a few altered samples show anomalously low δ41K and δ26Mg values. The δ41K and δ26Mg values do not correlate with K and Mg concentrations, or mineralogy of altered samples. The variable K-Mg isotope data likely reflect fluids of different physicalchemical properties, or different isotopic compositions. Based on the combined K-Mg isotope data, at least three groups of hydrothermal fluids are distinguished from the Dexing porphyry deposit. Therefore, K-Mg isotopes are potentially a novel tracer for fingerprinting fluids in complex hydrothermal systems.  相似文献   

辽宁赛马碱性岩体异性石化学成分特征及其蚀变组合对碱性岩浆-热液演化的指示意义     

邬斌  王汝成  刘晓东  郭国林  宋振涛 《岩石学报》2018,34(6):1741-1757

辽宁赛马碱性岩体早年因产铀矿而闻名,该岩体主要由响岩、霞石正长岩和异霞正长岩组成,其中铀、锆和稀土等元素矿化主要集中于异霞正长岩岩浆阶段。异性石是异霞正长岩中特征的锆-稀土矿物,主要分为两期,晚期异性石表现出更加富集Nb、REE等高场强元素的特点。早期异性石经历了一系列的热液蚀变,根据蚀变强弱程度,蚀变矿物组合可分为:(1)异性石+钠锆石+霓石±钠沸石;(2)异性石+钠锆石+锆石+钠沸石±霓石;(3)异性石假晶,假晶主要由残余异性石+钠锆石+锆石+钠沸石+霓石+钾长石+铈硅磷灰石组成。相比于岩浆锆石,蚀变组合中次生锆石具有富Ca、Al、Fe的特点,与异性石本身化学成分和流体性质密切相关。通过对异性石及其蚀变组合的精细矿物学研究,我们得知假晶的形成可能是异性石"溶解-再沉淀"的结果,致使假晶形成的流体至少包括:(1)占主导的富Na(±K)、Al、F的自交代流体;(2)少量晚期富Ca流体。假晶中次生锆石和铈硅磷灰石的结晶说明了Zr和REE等高场强元素的热液活动性,自交代碱性流体和富Ca流体在此过程中起到"搬运"和"提纯"的作用,这对认识碱性岩稀有、稀土成矿机制具有重要的指示意义。  相似文献   

从成岩-蚀变特征探讨塔深1井白云岩储层成因     

尤东华  王亮  胡文瑄  钱一雄  王小林  陈强路  张军涛 《岩石矿物学杂志》2018,37(1):34-46

塔深1井钻遇的寒武系地层属于中寒武统阿瓦塔格组和上寒武统丘里塔格下亚群。阿瓦塔格组以灰色-深灰色粉晶-细晶藻白云岩为主,丘里塔格下亚群以灰色-浅灰色晶粒结构白云岩与残余亮晶结构白云岩为主。藻白云岩在阴极发光下以明亮的中等强度砖红色-桔黄色为主要特点,具有相对偏重的δ18O值(-6.3‰~-4.5‰,平均为-5.3‰,VPDB)、相对较高的稀土总量以及与正常海相碳酸盐岩相似的稀土配分样式。晶粒白云岩与残余亮晶结构白云岩在阴极发光下以偏暗的中等强度蓝紫色-砖红色为主要特点,具有相对偏轻的δ18O值(-9.2‰~-5.7‰,平均为-7.5‰,VPDB)、相对偏低的稀土总量、Eu正异常与重稀土明显亏损为特点的稀土配分模式。阿瓦塔格组和丘里塔格下亚群白云岩在上述岩石学特征和地球化学特征上的差异表明储层发育的成岩-蚀变过程存在差异。研究认为,埋藏较深的阿瓦塔格组优质储层的形成受多种因素控制,其中准同生期大气淡水作用下石膏结核的溶解及非稳定碳酸盐矿物的溶解奠定了基础,后期成岩改造及流体作用进行了强化,局部遭充填破坏。  相似文献   

Destruction of Archean lower crust recorded in granulite and pyroxenite xenoliths of Mesozoic basalts from Western Liaoning,North China Craton     

Zou  Dongya  Zhang  Hongfu 《Contributions to Mineralogy and Petrology》2022,177(9):1-29

Contributions to Mineralogy and Petrology - Fractionation of felsic magma has been critical for the formation of high-silica rhyolites, chemical differentiation of the continental crust, and...  相似文献